{4-[(Diphenylphosphino)methylamino]pyridinium-κP}bis(nitrato-κO)silver(I)
نویسندگان
چکیده
In the title mononuclear complex, [Ag(C(18)H(18)N(2)P)(NO(3))(2)], the metal centre is coordinated in a slightly distorted trigonal-planar geometry by the P atom of the phosphine ligand and the O atoms of the two monodentate nitrate anions. In the crystal structure, complex mol-ecules are connected by inter-molecular N-H⋯O hydrogen bonds, forming chains running parallel to the b axis.
منابع مشابه
(Methanol-κO)(perchlorato-κO)bis(triphenylphosphine-κP)silver(I)
In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl-phosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol mol-ecule. The crystal structure is stablized by a bifurcated inter-molecular...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009